Spectroscopic investigations of phase-separated thermotropic layers based on UV cured acrylate resins

Macromolecular Symposia (2008)
December 2008 - Posted: 3/3/2012

--- In this paper spectroscopic techniques were adapted and applied to characterize the optical and morphological properties of thermotropic resins. Thermotropic films were prepared by variation of resin base and thermotropic additives. By UV/Vis/NIR spectroscopy the solar optical properties, the switching temperature, the switching process and the residual transmittance in the opaque state were determined. To control the sample temperature from ambient to 100?°C a conventional UV/Vis/NIR spectrophotometer equipped with an Ulbricht-sphere was adapted by a heating stage. Additive content, distribution and scattering domain size were characterized by Differential Scanning Calorimetry, Attenuated Total Reflectance spectroscopy and microscopic techniques ...
By: K. Resch, G.M. Wallner, R.W. Lang
Document Number: 265, 49-60

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